If I 1 = ∫ 0 ∞ x s i n x d x and I 2 = ∫ 0 ∞ x s i n 3 x d x
Now say k be, k = I 2 I 1 .
Let following summation be S . S = n = 1 ∑ ∞ ( 7 n − 6 n ) . ( 7 n + 1 − 6 n + 1 ) 7 n . 6 n
If a reaction from reactant A to product B have 1st order forward rate constant K and first order backward rate constant(from B back to A) K − 1 .
A B
Find the concentration of B(in M)= j after long time, if the initial concentration [ A ] o = 1 M and K = 1 s e c − 1 and K − 1 = 2 s e c − 1 . (Take initial concentration of B to be 0)
Input k × j × S
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To begin with, I 1 = ∫ 0 ∞ x sin x d x = ∫ 0 ∞ x sin 3 x d x = ∫ 0 ∞ x 3 sin x − 4 sin 3 x d x = 3 I 1 − 4 I 2 so that I 1 = 2 I 2 , and hence k = 2 .
Since ( 7 n − 6 n ) ( 7 n + 1 − 6 n + 1 ) 6 n × 7 n = 7 n − 6 n 6 n − 7 n + 1 − 6 n + 1 6 n + 1 we deduce that n = 1 ∑ N ( 7 n − 6 n ) ( 7 n + 1 − 6 n + 1 ) 6 n × 7 n = 6 − 7 N + 1 − 6 N + 1 6 N + 1 for any N , and hence S = 6 .
Finally, the differential equation − d t d [ A ] = [ A ] − 2 ( 1 − [ A ] ) = 3 [ A ] − 2 or d t d [ A ] + 3 [ A ] = 2 with the initial condition [ A ] ( 0 ) = 1 , has the solution [ A ] = 3 2 + 3 1 e − 3 t and so the concentration of B is [ B ] = 1 − [ A ] = 3 1 − 3 1 e − 3 t which converges to j = 3 1 as t → ∞ .
Thus k × j × S = 2 × 6 × 3 1 = 4 .