A chemistry problem by jaikirat sandhu

Chemistry Level 3

A 20 ml mixture of C O \ce{CO} and H X 2 \ce{H2} is reacted with excess oxygen at 300 K and 1 atm. The mixture exploded and is cooled. There was a volume contraction of 18 ml. If the volume ratio of C O \ce{CO} and H X 2 \ce{H2} in the original mixture was a b , \frac{a}{b}, where a a and b b are coprime integers, what is the value of a + b ? a+b?


The answer is 5.

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2 solutions

Jaikirat Sandhu
Apr 16, 2015

The answer is 3:2. 3 parts of CO.

Chew-Seong Cheong
Feb 22, 2016

The combustion reactions of C O \ce{CO} and O \ce{O} are as follows:

2 C O ( g ) + O X 2 ( g ) 2 C O X 2 ( g ) 2 H X 2 ( g ) + O X 2 ( g ) 2 H X 2 O ( l ) \ce{2 CO (g) + O2 (g) -> 2CO2 (g)} \\ \ce{2 H2 (g) + O2 (g) -> 2H2O} (l)

Let the volumes (moles) of C O \ce{CO} and O \ce{O} be x x and y y mL respectively. Therefore x + y = 20 x+y= 20 mL. The volumes of gases before and after the combustion are as follows:

x C O ( g ) + x 2 O X 2 ( g ) x C O X 2 ( g ) y H X 2 ( g ) + y 2 O X 2 ( g ) ( 0 ) H X 2 O ( l ) x\ce{CO (g)} + \frac{x}{2} \ce{O2 (g) ->} x \ce{CO2 (g)} \\ y \ce{H2 (g)} + \frac{y}{2} \ce{O2 (g) -> (0)H2O} (l)

x + x 2 + y + y 2 before combustion x after = 18 3 2 ( x + y ) x = 18 3 2 × 20 x = 18 30 x = 18 x = 30 18 = 12 mL y = 20 12 = 8 mL \begin{aligned} \Rightarrow \underbrace{x + \frac{x}{2} + y + \frac{y}{2}}_{\text{before combustion}} - \underbrace{x}_{\text{after}} & = 18 \\ \frac{3}{2}(x+y) - x & = 18 \\ \frac{3}{2} \times 20 - x & = 18 \\ 30 - x & = 18 \\ \Rightarrow x & = 30-18 = 12 \text{ mL} \\ \Rightarrow y & = 20 - 12 = 8 \text{ mL} \end{aligned}

x y = 12 8 = 3 2 a + b = 3 + 2 = 5 \Rightarrow \dfrac{x}{y} = \dfrac{12}{8} = \dfrac{3}{2} \quad \Rightarrow a + b = 3 + 2 = \boxed{5}

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