A 20 ml mixture of C O and H X 2 is reacted with excess oxygen at 300 K and 1 atm. The mixture exploded and is cooled. There was a volume contraction of 18 ml. If the volume ratio of C O and H X 2 in the original mixture was b a , where a and b are coprime integers, what is the value of a + b ?
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The combustion reactions of C O and O are as follows:
2 C O ( g ) + O X 2 ( g ) 2 C O X 2 ( g ) 2 H X 2 ( g ) + O X 2 ( g ) 2 H X 2 O ( l )
Let the volumes (moles) of C O and O be x and y mL respectively. Therefore x + y = 2 0 mL. The volumes of gases before and after the combustion are as follows:
x C O ( g ) + 2 x O X 2 ( g ) x C O X 2 ( g ) y H X 2 ( g ) + 2 y O X 2 ( g ) ( 0 ) H X 2 O ( l )
⇒ before combustion x + 2 x + y + 2 y − after x 2 3 ( x + y ) − x 2 3 × 2 0 − x 3 0 − x ⇒ x ⇒ y = 1 8 = 1 8 = 1 8 = 1 8 = 3 0 − 1 8 = 1 2 mL = 2 0 − 1 2 = 8 mL
⇒ y x = 8 1 2 = 2 3 ⇒ a + b = 3 + 2 = 5
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The answer is 3:2. 3 parts of CO.