An Unimaginatively named Chemistry Problem- Mole Concept.

Chemistry Level 2

Yawn what a boring name

A 10 gram sample of a mixture of Calcium Chloride and Sodium Chloride is treated with N a X 2 C O X 3 \ce{ Na2CO3 } to precipitate the Calcium as Calcium Carbonate. This C a C O X 3 \ce{ CaCO3 } is heated to convert all the Calcium to C a O \ce{CaO} and the final mass of C a O \ce{CaO} is 1.62 grams. What was the % by mass of C a C l X 2 \ce{CaCl2} in the original mixture?

Note: Report your answer up to 1 decimal place.


The answer is 32.1.

This section requires Javascript.
You are seeing this because something didn't load right. We suggest you, (a) try refreshing the page, (b) enabling javascript if it is disabled on your browser and, finally, (c) loading the non-javascript version of this page . We're sorry about the hassle.

3 solutions

Siddharth Singh
Jun 19, 2014

This problem is a cakewalk using the POAC method. There is another way of doing it which is quite algebraic and borders on stupidity.

Let there be x gram of C a C l 2 Ca{ Cl }_{ 2 } in the original mixture

We work our way backwards over here, so using POAC :

C a C O 3 C a O Ca{ CO }_{ 3 }\longrightarrow CaO

Balancing Ca :

Suppose y gram of C a C O 3 Ca{ CO }_{ 3 } produced 1.62 gram of CaO 1 × y 100 = 1 × 1.62 56 y = 162 56 1\times \frac { y }{ 100 } =1\times \frac { 1.62 }{ 56 } \\ \Rightarrow y=\frac { 162 }{ 56 }

Now we know how much of C a C O 3 Ca{ CO }_{ 3 } was produced by the reaction between C a C l 2 Ca{ Cl }_{ 2 } and N a 2 C O 3 { Na }_{ 2 }{ CO }_{ 3 }

So again using POAC

C a C l 2 C a C O 3 Ca{ Cl }_{ 2 }\longrightarrow Ca{ CO }_{ 3 }

Balancing Ca again,

1 × x 111 = 1 × 162 5600 x 3.21 1\times \frac { x }{ 111 } =1\times \frac { 162 }{ 5600 } \\ \Rightarrow x\approx 3.21

Therefore % of C a C l 2 Ca{ Cl }_{ 2 } in the original mixture=

3.21 10 × 100 \frac { 3.21 }{ 10 } \times 100 % = 32.1%

Using the molar mass of C a O \ce{CaO} as 56 56 g/mol, then 1.62 1.62 g of C a O = 1.62 56 = 0.0289 \ce{CaO} = \dfrac{1.62}{56} = 0.0289 mol.

Therefore, there is 0.0289 0.0289 mol of C a C l X 2 \ce{CaCl2} (molar mass = 111 = 111 g/mol) or 0.0289 × 111 = 3.2111 0.0289 \times 111 = 3.2111 g in the original sample, which is 3.2111 10 32.1 \dfrac{3.2111}{10} \approx \boxed{32.1} %.

Bernardo Sulzbach
Jun 21, 2014

Feed

((((1.62 g) / (CaO molar mass)) * (CaCl2 molar mass)) / (10 g)) * 100

To Wolfram|Alpha.

Step-by-step already written by Siddharth.

That's cheating man! :-/

Siddharth Singh - 6 years, 11 months ago

Log in to reply

How is it different from using a calculator or doing it with paper? I would rather look up MM(CaO) and MM(CaCl2) than approximate it to 56 and 110.

Besides, I wrote that expression. Getting the right expression is what solves the problem (IMHO).

Bernardo Sulzbach - 6 years, 11 months ago

0 pending reports

×

Problem Loading...

Note Loading...

Set Loading...