Start with a regular tetrahedron. On each of the faces build an identical regular three-sided pyramid so that the face of the tetrahedron is its base and the top of the pyramid is positioned directly outward from the center of the face. The height of the pyramids should be such that for each pair of adjacent pyramids their triangular sides lay in the same plane and create a single quadrilateral face. (The edge of the original tetrahedron will now be a diagonal in this quadrilateral.)
Find the measure of the smallest of the internal angles of this quadrilateral in degrees.
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The solid generated by this process is a cube, the quadrilateral is a square, and the smallest internal angle is 90 degrees.
This is easier seen going backward, starting with a cube and cutting off four pyramid-shaped corners.
But if you don't see it, you can start with the tetrahedron and grow pyramids as suggested. The resulting quadrilateral has to be a diamond, due to symmetry. So proving that both diagonals are the same length will prove that it is a square. The above is a projection of the tetrahedron into the plane of its base. All lengths and angles below are in this plane. The length of the side of the tetrahedron is arbitrarily picked to be 2. x is from a right triangle given by s i n ( 6 0 ) = 2 x 1 , therefore x = 2 × s i n ( 6 0 ) 1 . y is from another right triangle y = x × t a n ( 6 0 ) = 2 × c o s ( 6 0 ) 1 = 1 . y is half of the diagonal, so the entire diagonal is 2. (Since y is horizontal, it is not distorted.) The other diagonal, 2 x in the image, is distorted, but we know it's length. It is the length of the side of the tetrahedron, therefore also 2.