Chemistry Daily Challenge 29-July-2015
Three elements A, B, and C form three binary compounds. Each element has the same valence in these compounds. The mass fraction of A in the compound with B is 75%, and the mass fraction of B in the compound with C is 7.8%. Determine the percentage of C in the compound with A.
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Let the molecular masses of A , B and C be m A , m B and m C respectively. Then, we have:
⎩ ⎪ ⎨ ⎪ ⎧ m B m A = 0 . 2 5 0 . 7 5 m C m B = 0 . 9 2 2 0 . 0 7 8 ⇒ m A = 3 m B ⇒ m C = 1 1 . 8 2 0 5 m B
Then x = m A C m C = m A + m C m C = 3 m B + 1 1 . 8 2 0 5 m B 1 1 . 8 2 0 5 m B = 0 . 7 9 7 6 ≈ 7 9 . 8 %
This is pure mathematics for same valence in these compounds.
A + B A = 7 5 % = 4 3 ⟹ A B = 3 4 − 1 = 3 1
B + C B = 7 . 8 % = 5 0 0 3 9 ⟹ B C = 3 9 5 0 0 − 1 = 3 9 4 6 1
With A C = 1 1 7 4 6 1 ⟹ C A = 4 6 1 1 1 7 ,
A + C C = 1 + C A 1 = 1 + 4 6 1 1 1 7 1 = 5 7 8 4 6 1 × 1 0 0 % = (79.75778546712802768166089965397+)%
Answer: 7 9 . 8
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Aha! Missed It In First Attempt As I Gave the answer as 20.24% (which is actually the percentage of A In Compound Formed By A And C)
For The Sake Of Simplicity We Can Assume That Valencies Of All The Three
Elements Are 1 (You can take variable valencies as a,b,c etc but they are going
to cancel out in the end Because of the consequence of law of definite proportions) . so there is no need to mess your work .
Let The Molecular Masses Of Elements Be X, Y and Z Respectively .
Now Simply Plug In The Values In Data Provided
X/X+Y = 3/4
Y/Y+Z = 7.8/100
From Here We Can Get Values Of X And Z In Terms Of Y .
And What We Require is
Z/Z+X * 100
So we can simply substitute values of Z And X In The Above Equation
And On Calculation It Will Yield 79.8 (79.75899 to be precise)
Note - The Problem Might Be Attempted Using Laws of reciprocal proportions but it
will not yield the Correct Answer Because it is not applicable for Any three
pair of Elements . You can go on by law of equivalence as secondary method
of solving the problem