Can you solve it in first attempt?

Chemistry Level 3

Chemistry Daily Challenge \color{limegreen}{\underline{\text{Chemistry Daily Challenge }}} 29-July-2015 \color{#20A900}{\text{29-July-2015}}

Three elements A, B, and C form three binary compounds. Each element has the same valence in these compounds. The mass fraction of A in the compound with B is 75%, and the mass fraction of B in the compound with C is 7.8%. Determine the percentage of C in the compound with A.


The answer is 79.8.

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3 solutions

Prakhar Bindal
Jul 30, 2015

Aha! Missed It In First Attempt As I Gave the answer as 20.24% (which is actually the percentage of A In Compound Formed By A And C)

For The Sake Of Simplicity We Can Assume That Valencies Of All The Three

Elements Are 1 (You can take variable valencies as a,b,c etc but they are going

to cancel out in the end Because of the consequence of law of definite proportions) . so there is no need to mess your work .

Let The Molecular Masses Of Elements Be X, Y and Z Respectively .

Now Simply Plug In The Values In Data Provided

X/X+Y = 3/4

Y/Y+Z = 7.8/100

From Here We Can Get Values Of X And Z In Terms Of Y .

And What We Require is

Z/Z+X * 100

So we can simply substitute values of Z And X In The Above Equation

And On Calculation It Will Yield 79.8 (79.75899 to be precise)

Note - The Problem Might Be Attempted Using Laws of reciprocal proportions but it

will not yield the Correct Answer Because it is not applicable for Any three

pair of Elements . You can go on by law of equivalence as secondary method

of solving the problem

Let the molecular masses of A \ce{A} , B \ce{B} and C \ce{C} be m A m_A , m B m_B and m C m_C respectively. Then, we have:

{ m A m B = 0.75 0.25 m A = 3 m B m B m C = 0.078 0.922 m C = 11.8205 m B \begin{cases} \dfrac{m_A}{m_B} = \dfrac{0.75}{0.25} & \Rightarrow m_A = 3 m_B \\ \dfrac{m_B}{m_C} = \dfrac{0.078}{0.922} & \Rightarrow m_C = 11.8205 m_B \end{cases}

Then x = m C m A C = m C m A + m C = 11.8205 m B 3 m B + 11.8205 m B = 0.7976 79.8 % x = \dfrac{m_C}{m_{AC}} = \dfrac{m_C}{m_A+m_C} = \dfrac {11.8205 m_B}{3 m_B + 11.8205 m_B} = 0.7976 \approx \boxed{79.8} \%

Lu Chee Ket
Jan 26, 2016

This is pure mathematics for same valence in these compounds.

A A + B = 75 \frac{A}{A + B} = 75 % = 3 4 B A = 4 3 1 = 1 3 \frac34 \implies \frac{B}{A} = \frac43 -1 = \frac13

B B + C = 7.8 \frac{B}{B + C} = 7.8 % = 39 500 C B = 500 39 1 = 461 39 \frac{39}{500} \implies \frac{C}{B} = \frac{500}{39} -1 = \frac{461}{39}

With C A = 461 117 A C = 117 461 , \frac{C}{A} = \frac{461}{117} \implies \frac{A}{C} = \frac{117}{461},

C A + C = 1 1 + A C = 1 1 + 117 461 = 461 578 × 100 \frac{C}{A + C} = \frac{1}{1 + \frac{A}{C}} = \frac{1}{1 + \frac{117}{461}} = \frac{461}{578} \times 100 % = (79.75778546712802768166089965397+)%

Answer: 79.8 \boxed{79.8}

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