The rate of a reaction doubles when its temperature changes from 300 K to 310 K. What is the activation energy of such a reaction in kJ/mol?
Note: Use R = 8 . 3 1 4 J/K ⋅ mol and lo g 2 = 0 . 3 0 1 .
This section requires Javascript.
You are seeing this because something didn't load right. We suggest you, (a) try
refreshing the page, (b) enabling javascript if it is disabled on your browser and,
finally, (c)
loading the
non-javascript version of this page
. We're sorry about the hassle.
From arrhenius equation,logk2/k1= -Ea/2.303R (1/T2-1/T1) Given, k2/k1=2; T2=310K T1=300K On putting values, log2=-Ea/2.303*8.314(1/310-1/300) Ea=53598.6 J/mol=53.6 kJ/mol
l n k 2 k 1 = R E a ( T 1 1 − T 2 1 ) l n 2 1 = 8 . 3 1 4 E a ( 3 0 0 1 − 3 1 0 1 ) Calculating, E a = 5 3 5 9 4 . 2 8 J / m o l ≈ 5 3 . 6 k J / m o l
Problem Loading...
Note Loading...
Set Loading...
The rate of reaction k is given by Arrhenius equation k = A e − R T E a , where A is a frequency factor of the reaction, E a the activation energy, R the universal gas constant and T temperature in K. Therefore we have:
k 1 k 2 2 ln 2 ⇒ E a = A e R T 2 E a A e R T 1 E a = e 8 . 3 1 4 E a ( 3 0 0 1 − 3 1 0 1 ) = 8 . 3 1 4 E a ( 3 0 0 1 − 3 1 0 1 ) = 3 1 0 − 3 0 0 3 0 0 × 3 1 0 × 8 . 3 1 4 ln 2 = 5 3 5 9 4 . 3 = 5 3 . 6 k J / m o l