Pericyclic reactions have been used to generate cyclic structures in organic synthesis. This question explores one such reaction :
The product X has a three-fold rotational symmetry axis and is generated using the reaction given below:
With a basic understanding of this reaction, we move to a synthesis proposed by Chinese researchers in 2013 for an interesting alkaloid, M , isolated from the plants of the Daphiphyllum genus which is used in Chinese medicine to ease nausea. This reaction scheme is shown below:
Note that the stereocenter in B is enantiomerically isolated as an S isomer using PLE.
If denotes the number of rings in X and denotes the number of rings in M ,
Calculate the value of
BONUS
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