We have taken a saturated solution of AgBr , whose K s p is 1 2 × 1 0 − 1 4 . If 1 0 − 7 M of AgNO 3 is added to 1 L of this solution, what would be the conductivity (specific conductance) of the solution?
Given, λ ( A g + ) o = 6 × 1 0 − 3 S m 2 m o l − 1 λ ( B r − ) o = 8 × 1 0 − 3 S m 2 m o l − 1 λ ( N O 3 − ) o = 7 × 1 0 − 3 S m 2 m o l − 1
Express the answer in terms of 1 0 − 7 S m − 1 u n i t s
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Write the dissociation equilibria for AgBr Calculate the common ion concentration (Ag(+) And the resulting solubility of the salt Calculate the concentrations of all ions in solution And then simply use 1000*(Equivalent conductance of solution) = Sum of (Molar Conductances) * Concentrations} This should yield the answer