The given picture shows a system. The capacitor is initially charged till steady state and contains a dielectric of dielectric constant . The battery is connected in the whole experiment throught .
Our Aim with this setup is to use the magnitude of current developed in the circuit for electrolysis of and check what is the mass deposited on the cathode after a certain time from the beginning.
Initially, the capacitor plates are at a distance of . One of the plates is fixed and the other plate can be moved(after charging).
We start to move one of the plates with time-varying velocity .
The mass of Silver deposited in the time s to s be grams.
Input the value of
Details and Assumptions
a = 1
b = 2
d = 4
K = 10
t= 2 secs
Area of each plate = 100 .
is permeability of free space.
[The EMF of the battery]
Take Faraday's Constant as
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Fundamental capacitor equation:
Q = C V
Rate of change of charge:
Q ˙ = C V ˙ + V C ˙ = V C ˙
Capacitance formula:
C = d K ϵ 0 A C ˙ = − d 2 K ϵ 0 A d ˙
Plugging into charge rate of change:
Q ˙ = − d 2 V K ϵ 0 A d ˙ d ˙ = 2 a t + b
Total charge transfered (only magnitude matters):
Δ Q = ∫ 0 2 d 2 V K ϵ 0 A d ˙ d t = V K ϵ 0 A ∫ 0 2 d 2 d ˙ d t
We get one mole of silver for every mole of electrons. The number of moles of silver at the cathode is therefore:
N = F Δ Q
There are approximately 1 0 8 grams for each mole of silver. The total mass, in grams, is therefore:
M t o t = 1 0 8 F Δ Q = F 1 0 8 V K ϵ 0 A ∫ 0 2 d 2 d ˙ d t
Evaluating the integral numerically and plugging in numbers yields a total mass of 1 8 ϵ 0 grams.