Energetic Electrons

In atoms, electrons jump between energy levels, and they absorb or radiate energy in the form of light (photons). An electron falls to a lower energy level when it radiates a photon, and jumps to a higher energy level when it absorbs a photon.

Find the wavelength of the photon that radiates when an electron jumps from the n = 3 n = 3 energy level down to the n = 2 n = 2 energy level. Where is this photon in the electromagnetic spectrum?

Assumptions

  • h h (Planck's constant) = 4.14 × 1 0 15 4.14 \times 10^-15 eV s.
  • c c (Speed of light) = 3 × 1 0 8 3 \times 10^8 m/s.
  • All values are approximate.
  • Assume that this is a hydrogen atom.
It is in the visible red light spectrum with a wavelength of 656 nm. It is in the ultraviolet spectrum of wavelength equal to 121 nm. It is in the visible orange light spectrum of wavelength equal to 620 nm. It is in the visible blue light spectrum of wavelength equal to 467 nm.

This section requires Javascript.
You are seeing this because something didn't load right. We suggest you, (a) try refreshing the page, (b) enabling javascript if it is disabled on your browser and, finally, (c) loading the non-javascript version of this page . We're sorry about the hassle.

6 solutions

Discussions for this problem are now closed

Vitor da Silva
Apr 16, 2014

From level 3 to level 2 there is a loss of 1.89eV as radiation. We can use E=hf to find the frequency and then c=λf to find the wavelength.

You can also solve this problem using the Rydberg formula with Rydberg constant ( R ) = 1.097 × 1 0 7 m 1 (R)=1.097\times 10^7\quad m^{-1} and the transitioning levels are from n 2 = 3 n_2=3 to n 1 = 2 n_1=2 and since here hydrogen atom is considered, so Z = Z= Atomic no. of the considered element = 1 =1 .

The Rydberg formula is like this ----->

1 λ v a c = R Z 2 ( 1 n 1 2 1 n 2 2 ) \Large \frac{1}{\lambda_{vac}}=RZ^2(\frac{1}{n_1^2}-\frac{1}{n_2^2})

This formula is only applicable for hydrogen-like chemical elements.

Prasun Biswas - 7 years, 1 month ago

yes....thats true.prasun....how do find time for latex

Max B - 7 years, 1 month ago

It doesn't take time for me as I am habituated with writing in LaTeX.... ;)

Prasun Biswas - 7 years, 1 month ago

Calculation is good, but with this question I happen to have H-alpha solar telescope. This works on photons with a wavelength 656,28 nm wich is emitted by an electron when it drops from 3. to 2. orbital.

Martin Vällik - 7 years, 1 month ago

You can use de Broglie wavlength infact.

Kevin Patel - 7 years, 1 month ago
Namita Choudhary
Apr 19, 2014

E = 13.6 / n 2 E=-13.6/n^2 eV

h c / λ = 13.6 ( 1 / n 1 2 1 / n 2 2 ) e V = 13.6 ( 1 / 4 1 / 9 ) e V = 13.6 × 5 / 36 e V \begin{aligned} hc/\lambda&=-13.6\left(1/n_1^2-1/n_2^2\right) \rm{ eV} \\ &=-13.6\left(1/4-1/9\right) \rm{ eV}\\ &=-13.6 \times 5/36 \rm{ eV} \end{aligned}

λ = h c / 13.6 × 36 / 5 = 656 \lambda=hc/13.6\times 36/5 =656 nm

why is energy equal -13.6/n^2 eV i dont under stand please explain it for me

Ǯbd El-rhmaan M. Meky - 7 years, 1 month ago

Total energy of an electron is the sum of kinetic and potential energy, which comes out to be = -13.6 (Z^2)/(n^2) eV (Z being the atomic number and n the shell) . Since it is hydrogen, Z=1.

Abc Def - 7 years, 1 month ago
Gopar Caesar
Apr 21, 2014

from n-3 to n-2, -1,51-(-3,40) = 1,89 eV. E = (h.c)/λ 1,89eV.λ = h.c 1,89eV.λ = 4.14x10^-15eVs x 3x10^8m/s λ = 1.242^-6eV m/1,89eV λ = 6.57^-7m = 657nm 657nm is located on visible light range, and it is red

use hc=12400(app)

Rohit Purkait - 7 years, 1 month ago

wavelenth of emitted photon can be determined using the formula = 12400/(E2-E1), where E2, E1 are energy levels. When an electron jumps from outer to 2nd orbit the it lies in visible region. Thus 12400/(-1.5+3.4)=6526*10^-10 =>652nm

Well λ \lambda = h c E \dfrac{hc}{E} . We just need to compare Planck's equation and v = λ f v=\lambda\cdot f

Max B
Apr 18, 2014

from level 3 to level 2 it's balmer series..so visible range. use equations E=hf and then c=lambda.f

0 pending reports

×

Problem Loading...

Note Loading...

Set Loading...