Energy distribution

Nine particles are distributed on three energy levels with the energies E i = i E , i = 1 , 2 , 3 E_i = i \cdot E,\quad i = 1,2,3 so that we have total energy of U = n 1 E 1 + n 2 E 2 + n 3 E 3 = ( n 1 + 2 n 2 + 3 n 3 ) E = 16 E U = n_1 E_1 + n_2 E_2 + n_3 E_3 = (n_1 + 2 n_2 + 3 n_3 ) E = 16 E with the occupation numbers n i n_i of the state i i . These particle numbers meet the requirement N = n 1 + n 2 + n 3 = 9 N = n_1 + n_2 + n_3 = 9 For which choice of occupation numbers ( n 1 , n 2 , n 3 n_1,n_2, n_3 ) becomes the number of arrangement possibilities (microstates) maximal?

Bonus question: Calculate the particle numbers for the Boltzmann distribution n i exp ( E i / k T ) n_i \propto \exp(-E_i/k T) with a temperature k T = 3 E k T = 3 E . Which answer option comes next to the Boltzmann distribution?

( n 1 , n 2 , n 3 ) = ( 5 , 1 , 3 ) (n_1,n_2,n_3) = (5,1,3) ( n 1 , n 2 , n 3 ) = ( 4 , 3 , 2 ) (n_1,n_2,n_3) = (4,3,2) ( n 1 , n 2 , n 3 ) = ( 3 , 5 , 1 ) (n_1,n_2,n_3) = (3,5,1) ( n 1 , n 2 , n 3 ) = ( 2 , 7 , 0 ) (n_1,n_2,n_3) = (2,7,0)

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1 solution

Markus Michelmann
Nov 24, 2017

The number of permutations for a given choice of occupation numbers is Z ( n 1 , n 2 , n 3 ) = N ! n 1 ! n 2 ! n 3 ! Z(n_1,n_2,n_3) = \frac{N!}{n_1! \cdot n_2! \cdot n_3!} Therefore, the numbers of microstates are Z ( 2 , 7 , 0 ) = 36 Z ( 3 , 5 , 1 ) = Z ( 5 , 1 , 3 ) = 504 Z ( 4 , 3 , 2 ) = 1260 \begin{aligned} Z(2,7,0) &= 36 \\ Z(3,5,1) = Z(5,1,3) &= 504 \\ Z(4,3,2) &= 1260 \end{aligned} The most probable distribution ( n 1 , n 2 , n 3 ) = ( 4 , 3 , 2 ) (n_1,n_2,n_3) = (4,3,2) thus accounts for 55% of all possible microstates.

If we assume a Boltzmann distribution, the occupation numbers results n i = N e E i / k T i = 1 3 e E i / k T = 9 e i / 3 i = 1 3 e i / 3 ( n 1 , n 2 , n 3 ) ( 4.04 , 2.89 , 2.07 ) \begin{aligned} & \quad n_i = N \frac{e^{-E_i/k T}}{\sum_{i = 1}^3 e^{-E_i/k T}} = 9 \frac{e^{-i/3}}{\sum_{i = 1}^3 e^{-i/3}} \\ \Rightarrow & \quad (n_1,n_2,n_3) \approx (4.04, 2.89, 2.07) \end{aligned} which comes close to the distribution ( n 1 , n 2 , n 3 ) = ( 4 , 3 , 2 ) (n_1,n_2,n_3) = (4, 3, 2) . The Boltzmann distribution correspond to the most probable energy distribution for a given internal energy U U . For a large number N N of particles almost all microstates come close to the Boltzmann distribution.

Great problem! You have a typo in the solution.

Laszlo Mihaly - 3 years, 6 months ago

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