Energy of the dust

One thousand dust particles are trapped on a surface. The two states that a particle can occupy are

  • absorbed on the surface in a zero energy state.
  • excited with energy E 1 E_1 .

Suppose the particles are in thermal equilibrium at temperature T T , and 20 % of the particles are in the excited state. Find the value of 1 k B T i E i \frac{1}{k_BT}\sum_i E_i

Details and Assumptions

  • The particles are identical.
  • k B k_B is the Boltzmann constant.


The answer is 277.26.

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3 solutions

Josh Silverman Staff
Aug 5, 2013

The probability p i p_i for an equilibrium system to be in a given energy state is given by

p i exp E i / k B T \displaystyle p_i \sim \exp -E_i/k_BT .

For ease of writing, we can say γ i = E i / k B T \gamma_i = E_i/k_BT .

The two states states available to a dust particle on the surface are E = 0 , E 1 \displaystyle E = 0, E_1 .

For the energized state to have a probability p p we must have

p = e γ 1 1 + e γ 1 \displaystyle p = \frac{e^{-\gamma_1}}{1+e^{-\gamma_1}}

This is true if we have γ 1 = ln 1 p p \displaystyle \gamma_1 = \ln\frac{1-p}{p} .

The energy E 1 E_1 is then given by k B T ln 1 p p \displaystyle k_BT\ln\frac{1-p}{p} .

We know that 20% of the dust particles are in the energized state, so the total energy of all the dust particles is

E t o t a l = 200 E 1 = 200 ln 1 0.2 0.2 277 k B T \displaystyle E_{total} = \boxed{200E_1=\displaystyle 200\ln\frac{1-0.2}{0.2}\approx 277 k_BT}

i don't understand, why p = e γ i 1 + e γ i p = \frac{e^{-\gamma_i}}{1+e^{-\gamma_i}}

Ghany M - 7 years, 10 months ago

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Sure. The probability of each state is proportional to exp γ i \displaystyle\exp-\gamma_i , i.e. p i exp γ i \displaystyle p_i \sim \exp-\gamma_i .

But it is actually a more specific statement than that, each probability is proportional to exp γ i \displaystyle \exp-\gamma_i in the same way, i.e. the factor exp γ i \displaystyle \exp-\gamma_i becomes the true probability after it's normalized it by the sum over all the possible probability factors.

In the dust system, the two energy states are 0 0 and E 1 E_1 so the sum of all the probability factors is exp 0 + exp γ 1 = 1 + exp γ 1 \exp -0 + \exp-\gamma_1 = 1 + \exp-\gamma_1 . Does that make it any clearer?

Josh Silverman Staff - 7 years, 10 months ago

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oh yes, definitely. thank you :)

Ghany M - 7 years, 10 months ago
Pedro Osório
Aug 8, 2013

Using the canonical ensemble representation of the system, we know that the probability of each energy state is given by:

p i = 1 Z e E i k T 0 p_i = \frac{1}{Z} e^{-\frac{E_i}{kT_0}}

Where Z Z is just the normalizing constant:

Z = i p i Z = \sum_i p_i

Using this information and the fact that E 0 = 0 E_0 = 0 , we can see that the probability of being in energy state E 1 E_1 is:

p 1 = 1 Z e E 1 k T 0 1 + 1 Z e E 1 k T 0 p_1 = \frac{\frac{1}{Z} e^{-\frac{E_1}{kT_0}}}{1 + \frac{1}{Z} e^{-\frac{E_1}{kT_0}}}

With a bit of algebra after replacing p 1 w i t h 0.2 p_1 with 0.2 we get:

E 1 k T 0 = l n ( 0.25 ) 1.38629 \frac{E_1}{kT_0} = -ln(0.25) \approx 1.38629

Since 20% of the 1000 particles are in energy state 1 and the other particles have energy 0, we just need to multiply the above value by 200 to obtain the final answer.

The formula for p1 should obviously omit the 1/Z and the normalizing constant is the sum of the pi omitting the 1/Z factor. Can't find a way to edit it though.

Pedro Osório - 7 years, 10 months ago
David Vaknin
Feb 3, 2018

p 1 = 0.2 for E 1 p_1=0.2 \mbox{ for } E_1

p 0 = 0.8 for E 0 p_0=0.8 \mbox{ for } E_0

Boltzmann

p 1 / p 0 = e ( E 0 E 1 ) / k B T p_1/p_0=e^{(E_0-E_1)/k_BT}

ln ( 0.2 / 0.8 ) = ln 0.25 = 1.386.. = E 1 / k B T -\ln{(0.2/0.8)}=-\ln{0.25}=1.386.. = E_1/k_BT

s u m = 200 1.386.. = 277.26.. sum= 200*1.386..=277.26..

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