One thousand dust particles are trapped on a surface. The two states that a particle can occupy are
Suppose the particles are in thermal equilibrium at temperature T , and 20 % of the particles are in the excited state. Find the value of k B T 1 i ∑ E i
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i don't understand, why p = 1 + e − γ i e − γ i
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Sure. The probability of each state is proportional to exp − γ i , i.e. p i ∼ exp − γ i .
But it is actually a more specific statement than that, each probability is proportional to exp − γ i in the same way, i.e. the factor exp − γ i becomes the true probability after it's normalized it by the sum over all the possible probability factors.
In the dust system, the two energy states are 0 and E 1 so the sum of all the probability factors is exp − 0 + exp − γ 1 = 1 + exp − γ 1 . Does that make it any clearer?
Using the canonical ensemble representation of the system, we know that the probability of each energy state is given by:
p i = Z 1 e − k T 0 E i
Where Z is just the normalizing constant:
Z = ∑ i p i
Using this information and the fact that E 0 = 0 , we can see that the probability of being in energy state E 1 is:
p 1 = 1 + Z 1 e − k T 0 E 1 Z 1 e − k T 0 E 1
With a bit of algebra after replacing p 1 w i t h 0 . 2 we get:
k T 0 E 1 = − l n ( 0 . 2 5 ) ≈ 1 . 3 8 6 2 9
Since 20% of the 1000 particles are in energy state 1 and the other particles have energy 0, we just need to multiply the above value by 200 to obtain the final answer.
The formula for p1 should obviously omit the 1/Z and the normalizing constant is the sum of the pi omitting the 1/Z factor. Can't find a way to edit it though.
p 1 = 0 . 2 for E 1
p 0 = 0 . 8 for E 0
Boltzmann
p 1 / p 0 = e ( E 0 − E 1 ) / k B T
− ln ( 0 . 2 / 0 . 8 ) = − ln 0 . 2 5 = 1 . 3 8 6 . . = E 1 / k B T
s u m = 2 0 0 ∗ 1 . 3 8 6 . . = 2 7 7 . 2 6 . .
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The probability p i for an equilibrium system to be in a given energy state is given by
p i ∼ exp − E i / k B T .
For ease of writing, we can say γ i = E i / k B T .
The two states states available to a dust particle on the surface are E = 0 , E 1 .
For the energized state to have a probability p we must have
p = 1 + e − γ 1 e − γ 1
This is true if we have γ 1 = ln p 1 − p .
The energy E 1 is then given by k B T ln p 1 − p .
We know that 20% of the dust particles are in the energized state, so the total energy of all the dust particles is
E t o t a l = 2 0 0 E 1 = 2 0 0 ln 0 . 2 1 − 0 . 2 ≈ 2 7 7 k B T