Enthalpy of a reaction

Chemistry Level 2

The above shows the enthalpy change in the combustion reaction of methane (CH 4 _4 ) during the course of a reaction. Which of the following statements are correct? (The molecular weight of CH 4 _4 is 16. 16. )

a) This reaction is an exothermic reaction.

b) The temperature of surroundings goes down when the reaction occurs.

c) The enthalpy of reactants is greater than that of products.

d) The magnitude of enthalpy change when 8 8 g of CH 4 _4 is completely combusted is 890.8 890.8 kJ.

a) and b) a) and c) b) and d) b), c) and d)

This section requires Javascript.
You are seeing this because something didn't load right. We suggest you, (a) try refreshing the page, (b) enabling javascript if it is disabled on your browser and, finally, (c) loading the non-javascript version of this page . We're sorry about the hassle.

2 solutions

Chew-Seong Cheong
Feb 15, 2016

a) This reaction is an exothermic reaction. T r u e \color{#3D99F6}{True}

  • An exothermic reaction releases energy such as heat to the surroundings. The graph shows that the reactants C H X 4 \ce{CH4} and O X 2 \ce{O2} have a higher energy than that of the products C O X 2 \ce{CO2} and H X 2 O \ce{H2O} . Therefore, the reaction releases energy, which is heat, to the surroundings and it is exothermic.

b) The temperature of surroundings goes down when the reaction occurs. F a l s e \color{#D61F06}{False}

  • As heat is released to the surroundings, it raises its temperature and lowers it. Whereas, an endothermic (the opposite of exothermic) reaction absorbs heat from the surroundings and lower its temperature.

c) The enthalpy of reactants is greater than that of products. T r u e \color{#3D99F6}{True}

  • Enthalpy H H is a measure of energy. As the reactants have a higher energy level therefore a higher enthalpy than that of reactants. For an exothermic reaction, enthalpy change Δ H = H p r o d u c t s H r e a c t a n t s > 0 \Delta H = H_{products} - H_{reactants} > 0 (negative), therefore, H r e a c t a n t s > H p r o d u c t s H_{reactants} > H_{products} .

d) The magnitude of enthalpy change when 8 8 g of C H X 4 \ce{CH4} is completely combusted is 890.8 890.8 kJ. F a l s e \color{#D61F06}{False}

  • The enthalpy change Δ H \Delta H is 890.8 -890.8 kJ per mole or 16 16 g of C H X 4 \ce{CH4} , but 8 8 g is only half a mole.
Sand Eee
Mar 5, 2014

basic question

How so???

Tanya Gupta - 7 years, 3 months ago

Log in to reply

Option a: All combustion reactions exhales energy otherwise oxethermic - TRUE

Option b: Temperature of the surroundings go up after combustion not go down - FALSE

Option c: Energy to the surroundings comes from the enthaly of reactants, hence products must have less enthalpy than reactants so as not to violate law of conservation of energy - TRUE

Option d: I really did not work this out, but know for sure A and C are correct, hence eliminated this from the options

John Samuel - 7 years, 2 months ago

Log in to reply

My mistake...thanks for the solution...I think I can clear up d)...It would probably be 890.8kJ if 1 mole of CH4 is taken...they mentioned that only 8 gm is taken

Tanya Gupta - 7 years, 2 months ago

0 pending reports

×

Problem Loading...

Note Loading...

Set Loading...