The angle made by the log P vs. log V graph on x axis is
Assumptions: P is pressure V is Volume Temperature is constant.
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It is a fact that lo g P = lo g n R T − lo g V for an ideal gas; this is a consequence of the ideal gas law. Assuming the author meant that it is an isothermal process, lo g P = C − lo g V where C is a constant. This is a line of slope m = − 1 which means the angle with respect to the V axis is arctan ( − 1 ) = − 4 5 ∘ Now the answer is a matter of semantics and poor definition. Since 4 5 ∘ isn't an answer, perhaps it is the supplementary angle which constructs the same slope: 1 8 0 ∘ − 4 5 ∘ = 1 3 5 ∘ which is an answer.