The rate of the reaction is given by
If and doubles and is halved, what is the change in the half-life of
This section requires Javascript.
You are seeing this because something didn't load right. We suggest you, (a) try
refreshing the page, (b) enabling javascript if it is disabled on your browser and,
finally, (c)
loading the
non-javascript version of this page
. We're sorry about the hassle.
For this question, we know that the half-life of a particular reactant, A is given by t 1 / 2 = k l n 2 , for R a t e = k [ A ] However, do note that this only applies for a first-order reaction, and hence, cannot be applied directly.
Consider this : R a t e = k [ A ] [ B ] 2 [ C ] 3
= R a t e = k [ C ] 3 [ B ] 2 [ A ]
= R a t e = k ′ [ A ] , where k ′ = k [ C ] 3 [ B ] 2
Hence, the half-life for A is given by t 1 / 2 = k ′ l n 2 , which simplifies to
t 1 / 2 = k [ C ] 3 [ B ] 2 l n 2
With that, for doubling [ B ] while halving [ C ] , the overall change in the denominator is that it is half of the original. Hence, the t 1 / 2 is d o u b l e d
This form of using k ′ to substitute reactant concentration is known as a "Pseudo-first-order" reaction.
Note that a change in [ A ] does NOT affect its own half-life
http://en.wikipedia.org/wiki/Rate_equation