Inspired By A JEE 2014 Question

The radiation corresponding to the 2 1 2\rightarrow 1 transition of hydrogen atom falls on a metal surface to produce photoelectrons. These electrons are made to enter an electric field of 1 0 5 N/C 10^{-5} \text{ N/C} as shown in the figure. If the electrons just change their direction of motion after 1 second, then the work function of the metal is close to which of the following choices?

Details and Assumptions :

  • Take the mass of electron, m e = 9.1 × 1 0 31 kg m_{e}=9.1\times 10^{-31}\text{ kg} ,

  • The charge on electron, e = 1.6 × 1 0 19 C e=-1.6\times 10^{-19}\text{ C} and 1 eV = 1.6 × 1 0 19 J 1\text{ eV}=1.6\times 10^{-19}\text{ J} .

  • The Ionization energy of Hydrogen atom in ground state is 13.6 e V 13.6 eV

0.8 eV 0.8\text {eV} 1.8 eV 1.8\text {eV} 1.1 eV 1.1\text {eV} 1.4 eV 1.4\text {eV}

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1 solution

Arjen Vreugdenhil
Mar 26, 2016

The acceleration of the electron is a = e E m e . a = -\frac{eE}{m_e}. If it reaches zero speed after time t t , it's initial velocity must have been v 0 = a t = e E t m e , v_0 = -at = \frac{eEt}{m_e}, which means it had a kinetic energy of K 0 = 1 2 m e v 2 = e 2 E 2 t 2 2 m e = 8.8 e V . K_0 = \tfrac12m_ev^2 = \frac{e^2E^2t^2}{2m_e} = 8.8\:e\ \text{V}. (To find the energy in eV, I simply left one factor e e out.)

The photon that was released had energy E γ = ( E 1 E 2 ) = Ry 1 2 Ry 2 2 = 3 4 Ry , E_\gamma = -(E_1 - E_2) = \frac{\text{Ry}}{1^2} - \frac{\text{Ry}}{2^2} = \tfrac34\text{Ry}, where Ry = 13.6 eV \text{Ry} = 13.6\ \text{eV} is the well-known ionization energy of the electron in hydrogen in its ground state. The work function of the metal, then, is ϕ = E γ K 0 = 10.2 eV 8.8 eV = 1.4 eV . \phi = E_\gamma - K_0 = 10.2\ \text{eV} - 8.8\ \text{eV} = \boxed{1.4}\ \text{eV}.

Nice solution!

Sahil Bansal - 5 years, 2 months ago

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