The time taken to freeze water present in an open container with insulated walls is of the form where is a constant, is the density of water, is the latent heat of fusion of water, is the height of the water column, is the thermal conductivity of ice and is the temperature of the surroundings.Assume that the initial temperature of water is .
Find
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Let us assume that x depth of ice is already formed and a layer of thickness d x of ice is forming,
Let A be the area, V be the volume of the container and M be the mass of water present.
So, d m = V M × d x × A
d m = ρ w × A × d x
Now, the heat change d Q = d m × L
= ρ w × A × d x × L
And now, using d t d Q = l k A △ T ,
d t d Q = x k A T
d t ρ w A d x L = x k A T
ρ w A L x d x = k A T d t
Now, integrating x from 0 to h and t i m e from 0 to t ,
∫ 0 h ρ w A L x d x = ∫ 0 t k A T d t
We finally get T i m e = 2 k T ρ w L h 2
So, 4 c 1 + a + b + c + d + e = 4