Keeping it together

The "binding energy" of a nucleus is the total energy of the bonds between the nucleons (the protons and neutrons) in the nucleus. Consider a neutral atom with Z Z protons and N N neutrons in the nucleus, and let the total nucleon number A be given by A = Z + N A=Z+N . The binding energy can be written as a function of Z Z and A A as:

E ( A , Z ) = a v A a s A 2 / 3 a c Z 2 A 1 / 3 E_{(A,Z)}=a_vA-a_sA^{2/3}-a_cZ^2A^{-1/3}- a a ( A 2 Z ) 2 A 1 / 4 + δ A 1 / 2 a_a(A-2Z)^2A^{-1}/4+\delta A^{-1/2} .

The values for the parameters in the above equation are a v = 15.67 MeV , a s = 17.23 MeV , a c = 0.714 MeV , a a = 93.15 MeV a_v=15.67~\mbox{MeV}, a_s=17.23~\mbox{MeV}, a_c=0.714~\mbox{MeV}, a_a=93.15~\mbox{MeV} .

δ \delta can take different values depending on whether A and Z are even or odd. To simplify the calculation, we'll let δ = 0 \delta = 0 , which is one of the allowed values.

The nucleus is the most stable when the binding energy is highest, as that's when it takes the most energy to rip it apart. When A A is small, we get Z = A / 2 Z=A/2 for the most stable nuclei, and this explains why for lighter atoms half of the nucleus is generally protons and the other half is made from neutrons. When A A is large, the most stable nuclei (the ones with highest binding energy) have Z A 1 y = A w Z \sim A^{1-y} = A^w . Find w w .

Details and assumptions

  • Take the true large A limit. Real nuclei of course stop occurring in nature as A increases but if you look at the periodic table you will start to see the trend towards the value of w w you calculate.


The answer is 0.333.

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2 solutions

Vostro Del
May 20, 2014

for an element with given value of A,for binding energy to be maximum

differentiation of E w.r.t Z keeping A constant must be Zero.

i.e. - 2a cZA^{-1/3} + a a{A-2Z}A^{-1} = 0

which gives Z=a a A / { 2a a + 2a_cA^{2/3} }

since a c is very much less than a a. so for elements with low mass number(A),second term of denominator can be neglected giving

Z=A/2,

But in case of elements with high mass number,the things are opposite

here first term of denominator is neglected giving

Z ~ A^{1 - 1/3} = A^{0.333}

David Mattingly Staff
May 13, 2014

OK, cool, this is a brute-force problem: we just need to find the value of Z Z to maximize E ( A , Z ) E(A,Z) with the value of A A fixed by setting the derivative of E ( A , Z ) E(A,Z) with respect to Z Z equal to 0 0 . The final result is pretty straightforward: Z = A 2 a c a a A 2 / 3 + 2 Z = \frac{A}{2\frac{a_c}{a_a} A^{2/3} + 2} With large A A , Z = a a 2 a c A 1 / 3 Z=\frac{a_a}{2a_c} A^{1/3} , so w = 1 / 3 w=1/3 .

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