of pure water at saturated with gas yielded a solution of density and containing by mass. Let the volume of solution resulting be and the volume of gas at and pressure used to saturate water be . Find
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Let the masses of H X 2 O and N H X 3 in the solution be m H X 2 O and m N H X 3 respectively. Then, m H X 2 O = 1 0 5 g and:
m N H X 3 + m H X 2 O m N H X 3 m N H X 3 0 . 7 m N H X 3 ⇒ m N H X 3 = 0 . 3 = 0 . 3 m N H X 3 + 0 . 3 m H X 2 O = 0 . 3 m H X 2 O = 0 . 7 0 . 3 m H X 2 O = 0 . 7 0 . 3 × 1 0 5 = 4 5 g
The volume of the solution,
A = density of solution mass of solution = 0 . 9 m N H X 3 + m H X 2 O = 0 . 9 4 5 + 1 0 5 = 1 6 6 . 6 6 7 g
The volume of 45 g of N H X 3 at STP ( 0 ∘ C, 760 mm Hg ):
V S T P = molar mass of N H X 3 4 5 × 2 2 . 4 = 1 7 4 5 × 2 2 . 4 = 59.294 L
Using T p V = constant , the volume of 45 g of N H X 3 at 4 ∘ C, 775 mm Hg :
2 7 7 7 7 5 B ⇒ B = 2 7 3 7 6 0 V S T P = 2 7 3 × 7 7 5 2 7 7 × 7 6 0 × 5 9 . 2 9 4 = 58.998 L
Therefore, A + B = 1 6 6 . 6 6 7 + 5 8 . 9 9 8 = 2 2 5 . 6 7