Nitric acid reacts with oxides

Chemistry Level 2

Burning 2.23 2.23 grams of a mixture X X containing F e , A l , Z n \ce{Fe},\ce{Al},\ce{Zn} and M g \ce{Mg} completely in oxygen gives us 2.71 2.71 grams of a mixture Y Y . Dissolve the mixture Y Y in excessive nitric acid H N O X 3 \ce{HNO_3} solution. We gain 0.672 0.672 liters of N O \ce{NO} (in standard conditions) as the only nitric oxide produced during the reaction.

How much H N O X 3 \ce{HNO_3} had reacted? Type your answer in moles ( m o l mol ). Round your answer to 2 decimal places.

Calculate using the given molar mass below:

F e = 56 , A l = 27 , Z n = 65 , M g = 24 , O = 16 , H = 1 , N = 12 \ce{Fe}=56, \ce{Al}=27, \ce{Zn}=65, \ce{Mg}=24, \ce{O} = 16, \ce{H}=1, \ce{N}=12


The answer is 0.18.

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1 solution

The added weight to Y Y is the oxygen added to X hence n O = m Y m X 16 = 2.71 2.23 16 = 0.03 moles \displaystyle n_{O} = \frac{m_{Y}-m_{X}}{16} = \frac{2.71-2.23}{16} = 0.03 \text{ moles}

n N O 2 = 0.672 22.4 = 0.03 moles \displaystyle n_{NO_{2}} = \frac{0.672}{22.4} = 0.03 \text{ moles}

Know that 2 H + + O 2 H 2 O 2H^{+} + O^{2-} \to H_{2}O

and 4 H + + N O 3 N O + 2 H 2 O 4H^{+} + NO_{3}^{-} \to NO + 2H_{2}O

n H N O 3 = 2 n O + 4 n N O 2 = 2 × 0.03 + 4 × 0.03 = 0.18 moles \displaystyle \implies n_{HNO_{3}} = 2n_{O} + 4n_{NO_{2}} = 2 \times 0.03 + 4 \times 0.03 = \orange{\boxed{0.18}} \text{ moles}

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