Calculate the minimum work required to compress 24g of oxygen at 298K from a pressure of 1 atm to a pressure of 50 atm.
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We will make our initial calculations using P V = n R T , and then solve for variables to plug into W = n R T ∗ l n ( V i V f ) . Since we're calculating the answer in Joules and using Kelvin, we'll use the gas constant R in units of J/mol*K.
R = 8 . 3 1 4 J / mol K .
P i = 1 atm
n = g of Oxygen / atomic mass of Oxygen = 1 5 . 9 9 9 g / m o l 2 4 g → n = 1 . 5 0 0 mols
T = 2 9 8 K
Solving for V i by plugging these values into P V = n R T gives...
( 1 a t m ) V i = ( 1 . 5 0 0 ) ( 8 . 3 1 4 ) ( 2 9 8 ) → V i = 3 6 . 6 8
So, now that we know the initial Volume, we can calculate the final Volume using the final Pressure P f = 5 0 atm.
( 5 0 a t m ) V f = ( 1 . 5 0 0 ) ( 8 . 3 1 4 ) ( 2 9 8 ) → V f = 0 . 7 3 3 7
Now we can plug these into W = n R T ∗ l n ( V i V f ) to find the work.
Solving for W gives: W ≈ − 7 2 7 0 . 5 5 J