The half life time of reaction is halved when the initial concentration of reactant is doubled.The order of reaction is
To solve this problem, you need to know Half life time
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General Expression for half life time for n t h order reaction is given by t 1 / 2 = ( n − 1 ) k C n − 1 2 n − 1 − 1 See proof here: Half life time
That is
t
1
/
2
∝
C
0
1
−
n
When initial Concentration
C
0
is doubled, half life time
t
1
/
2
is reduced to half.
Taking ratio,
1
/
2
1
=
(
2
1
)
1
−
n
That is
2
=
2
n
−
1
which gives
n
=
2
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For a reaction A → B , let the order be n . Therefore, we can write, − dt d a = k a n . Rearranging and integrating, we obtain, ∫ a 0 a − a n d a = ∫ 0 t k d t ⇒ n − 1 1 ( a n − 1 1 − a 0 n − 1 1 ) = k t .
At half life time, t = T 1 / 2 and a = 2 a 0 . Substituting it in the above equation, we get, ( n − 1 ) a 0 n − 1 1 ( 2 n − 1 1 − 1 ) = k T 1 / 2 .
Therefore, T 1 / 2 ∝ a 0 n − 1 1 . Here we realize, T 1 / 2 ∝ a 0 1 . On comparing the two, we can write, n − 1 = 1 ⇒ n = 2 .
Note:
a denotes the concentration of A at any time t while a 0 is its initial concentration. T 1 / 2 is the half life time of the reaction