Order of reaction 2

Chemistry Level 2

The half life time of reaction is halved when the initial concentration of reactant is doubled.The order of reaction is

To solve this problem, you need to know Half life time

2 0.5 1 0

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2 solutions

Sudeep Salgia
Jul 15, 2015

For a reaction A B A \rightarrow B , let the order be n n . Therefore, we can write, d a dt = k a n \displaystyle -\frac{\text{d}a}{\text{dt}} = k a^n . Rearranging and integrating, we obtain, a 0 a d a a n = 0 t k d t 1 n 1 ( 1 a n 1 1 a 0 n 1 ) = k t \displaystyle \int_{a_0}^a -\frac{\text{d}a}{a^n} = \int_0^t k \text{ d}t \Rightarrow \frac{1}{n-1} \left( \frac{1}{a^{n-1}} - \frac{1}{a_0^{n-1}} \right) = kt .

At half life time, t = T 1 / 2 t = T_{1/2} and a = a 0 2 a = \dfrac{a_0}{2} . Substituting it in the above equation, we get, 1 ( n 1 ) a 0 n 1 ( 1 2 n 1 1 ) = k T 1 / 2 \displaystyle \frac{1}{(n-1 )a_0^{n-1}} \left( \frac{1}{2^{n-1}} - 1 \right) = kT_{1/2} .

Therefore, T 1 / 2 1 a 0 n 1 \displaystyle T_{1/2} \propto \frac{1}{a_0^{n-1}} . Here we realize, T 1 / 2 1 a 0 T_{1/2} \propto \frac{1}{a_0} . On comparing the two, we can write, n 1 = 1 n = 2 n-1 = 1 \Rightarrow \boxed{n=2} .

Note:

a a denotes the concentration of A A at any time t t while a 0 a_0 is its initial concentration. T 1 / 2 T_{1/2} is the half life time of the reaction

General Expression for half life time for n t h n^{th} order reaction is given by t 1 / 2 = 2 n 1 1 ( n 1 ) k C n 1 t_{1/2}=\frac{2^{n-1}-1}{(n-1)kC^{n-1}} See proof here: Half life time

That is t 1 / 2 C 0 1 n t_{1/2} \propto {C_0}^{1-n} When initial Concentration C 0 C_0 is doubled, half life time t 1 / 2 t_{1/2} is reduced to half. Taking ratio, 1 1 / 2 = ( 1 2 ) 1 n \frac{1}{1/2}=(\frac{1}{2})^{1-n} That is 2 = 2 n 1 2=2^{n-1} which gives
n = 2 \boxed{n=2}

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