Organic Chemistry

Chemistry Level 2

Formaldehyde reacts with Grignard reagent (methyl magnesium iodide) to form which of the following?

Isopropyl Alcohol Ethyl Alcohol Methyl Alcohol Benzaldehyde

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2 solutions

Chew-Seong Cheong
Feb 15, 2016

The mechanism of Grignard reaction is given below.

Image from Grignard reaction

Since the reactant is formaldehyde (methanal) and the Grignard reagent is methyl magnesium iodide (with I \ce{I} replacing B r \ce{Br} ), then R = C H X 3 \ce{R = CH3} and the reaction is:

H C H O + C H X 3 M g I C H X 3 C H O H \ce{HCHO + CH3 Mg I -> -> -> CH3CHOH}

The end product of the reaction is ethyl alcohol \boxed{\text{ethyl alcohol}} (ethanol).

Lu Chee Ket
Feb 12, 2016

C H 3 M g I + H C H O C H 3 C H 2 O + M g 2 + + I CH_3MgI + HCHO \rightarrow CH_3CH_2O^- + Mg^{2+} + I^-

C H 3 C H 2 O + H 2 O C H 3 C H 2 O H + O H CH_3CH_2O^- + H_2O \rightarrow CH_3CH_2OH + OH^-

Methyl magnesium iodide becomes ethyl alcohol. Formaldehyde is methanal.

Answer: E t h y l A l c o h o l \boxed{Ethyl~Alcohol}

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