In which of the following compounds the oxidation number of sulphur is ?
A.
B.
C.
D.
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Maximum Oxidation Number of an Element is it’s Valence electrons (or) it’s Group number .
So, the maximum oxidation number of Sulphur is +6 because sulphur has 6 valence electrons.
Therefore, The oxidation number of Sulphur cannot be +7 as it's maximum oxidation number is +6 .
If the oxidation number of sulphur in a compound exceeds + 6 (as in N a 2 S 2 O 3 ) it indicates the presence of peroxy linkages.