A chamber of volume 1 0 0 0 cm 3 is evacuated by a pump at constant temperature whose evactuation rate is equal to 5 0 cm 3 s − 1 .
Find the time in which the pressure of the chamber reduces to e times the original pressure.
Take e = 2 . 7 1 8 2 … .
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In a time d t gas expands from V to V + d V .
We use-
P V = ( P − d P ) ( V + d V )
P d P = − V d V
Also, d t d V = evactuation rate
Integrating the expression, we get,
t = l n ( e ) . 5 0 1 0 0 0
t = 2 0 seconds
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T = const, so
p 1 V 1 = p 2 V 2 p V = ( p + d p ) ( V + s d t ) , , where s = d t d V
p V = p V + d p V + p s d t + s d p d t ; − V d p = p s d t + s d p d t , s d p d t = 0 ; − V d p = p s d t ; d p / p = − s d t / V ; p = C e − V s t
At t=0 p = p 0 , so C = p 0 p 0 / p = e V s t = 1 t = s V = 5 0 1 0 0 0 = 2 0 s