Salted tea

Say I have two identical cups of tea, with equal volume and temperature. I pour into one cup a spoonful of salt, and the other I leave untouched. I stir both cups with identical rods at the same rate.

After some time, predict which cup will have a lower temperature.

Note: Salt doesn't react chemically with tea. Assume the salt is the same temperature as the tea.

Image credit: Wikipedia PierreSelim
Salted Unsalted

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6 solutions

Jake Lai
Jun 15, 2015

Think about magnets: unlike poles - north and south - attract , as we all know.

Salt is a crystal made up of a lattice structure formed mainly from sodium and chlorine atoms; hence, sodium chloride.

Sodium has only one valence electrons and thus readily loses its valence electron due to the relatively small nuclear charge; chlorine, on the other hand, has a greater nuclear charge, causing it to hold into its electrons more tightly. In other words, sodium is electropositive, whereas chlorine is electronegative .

In sodium chloride's ionic bond, sodium donates its lone valence electron to chlorine, which accepts the electron. This can be likened to magnets in that the sodium, now a positive ion - cation - is attracted to chloride, now a negative ion - anion .

When salt is mixed with tea, it dissolves; this is an endothermic reaction, ie it absorbs heat from its environment . This in chemistry/physics is known as enthalpy of solution: the change in thermal energy when dissolving a substance in a solvent. But why exactly is this?

That's where the magnet analogy comes in. When you pull apart two magnets, you need to do work, which adds energy to the system of magnets , specifically potential energy. In the same way, bonds in salt are being broken; this adds energy to the system - potential energy as well. Where is this energy drawn from? The small-scale vibrations of atoms: heat . If you shake two attached magnets violently enough, they too will come apart.

So putting this altogether, we now know the reason why salted tea is cooler than unsalted tea.

Can it be like this: Salt is a non-volatile solute. So, adding it to tea will decrease the formation of vapour pressure. Less is the formation of vapour pressure, less will be evaporation. Evaporation causes coolness (the way refrigrators work). So, if there will be less evaporation, more will be the temperature. So, according to this the salted tea will have more temperature. Reply @Jake Lai

Ðeepanshu Kumar - 5 years, 11 months ago

Thank you to Michael Horton, who kindly pointed out that I mistook "latent heat of fusion" for "enthalpy of solution"!

Jake Lai - 5 years, 12 months ago

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But, Jake, as a result of that mistake, the answer is wrong. Exothermic reactions give off heat to their surroundings. Since the salt's surrounding is the tea, the tea will get hotter, not cooler. And since this process has little to do with vibrations, the rest of the explanation needs re-writing also.

Michael Horton - 5 years, 11 months ago

So, put a pinch of salt in your tea when you have an urge of going somewhere faster! ¨ \huge\ddot\smile

It was a very nice question, with a very neat explanation! +1

Sravanth C. - 5 years, 12 months ago
Michael Horton
Jun 18, 2015

I must say that this is the most beautifully written wrong answer that I've seen! Latent heat of fusion is for melting, not dissolving. The thing that is involved here is standard enthalpy of solution. The SEP for NaCl is +3.88 kj/mol meaning that table salt gives off heat when it dissolves and the salted water will be hotter. There's much debate over whether dissolving is a chemical or physical change, so it's best to avoid calling it endothermic or exothermic reaction. Therefore, both the answer and the explanation are incorrect.

You had me scared for a minute there. Thank you so much for the catch on latent heat of fusion though!

Jake Lai - 5 years, 12 months ago

i see he not much wrong except in saying latent heat of fusion but the disslove of salt in water is known to be endothermic reaction and it decrease the temperature of water Although jake you shall note that the logic you made is very intuitive and not always right because simply you can't ignore other substance and you must have in ur mind enthlapy heat for each of substance in ionization process you have in case of NaOH disslove in water is exothermic reaction and temperature of water increase

Mahmod Abass - 5 years, 11 months ago
Ahmed Ali
Jul 28, 2015

The heat energy of the tea is used in breaking the ionic bonds of sodium and chloride ions. Hence the overall heat energy of tea is reduced, bringing it to a lower temperature than the unsalted one.

Jonathan Alvaro
Jun 29, 2015

Not to sound arrogant, but I think there's a simpler solution with the law of physics. When something is put into a hotter liquid then some heat energy will be transferred from the liquid to the object. Thus, the temperature of the tea with salt will be lower the moment the salt is added. Then, considering both cups of tea are identical, then they release the same amount of heat/second. This means that both cups' temperature decreases at the same rate. So, the salted tea will be colder.

Rick Foster
Jun 16, 2015

The volume of water is reduced by the presence of salt, the lower the volume, the quicker the temperature drops.

What if the salt was at the same temperature as the tea?

Jake Lai - 5 years, 12 months ago
Tushar Kaushik
Jun 18, 2015

this is because sal ansorbs heat. try it..... hold a ice cube in your hand along with some salt. after some ime it will become difficult to hold it

In responce to Tusher ... That happens as it forms ice-mixture but does it also do the same work in warm medium?

Debjit Biswas - 5 years, 11 months ago

Salt-water has a lower freezing point than water.

Justin Mellon - 5 years, 11 months ago

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