Suppose that the free energy of a system is described by
where
is the temperature, and
represents some property of the system, such as its overall magnetization. As
rises and falls, but does not cross
, the allowed physical value(s) of
,
change somewhat (see Assumptions).
When crosses , however, there is a qualitative shift in the allowed values of , and the system undergoes a phase transition.
Suppose we're working with the system at a temperature below such that , find .
Assumptions
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F = 4 m 4 − 1 0 m 2 , f o r c r i t i c a l v a l u e , d m d F = 0 ⇒ m 3 − 2 0 m = 0 ⇒ m = 4 . 4 7 2 1 3 5 9 5 5 ( a s m > 0 )