Stability Predictions

Chemistry Level 1

Based on bond order, which molecule or ion would you expect to have the shortest bond length and the largest bond energy?

H e X 2 X + \ce{He2+} H X 2 X + \ce{H2^+} H e X 2 \ce{He2} H X 2 \ce{H2}

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1 solution

Jordan Calmes
Feb 11, 2016

The bond orders are as follows:

H X 2 \ce{H2} = 1

H X 2 X + \ce{H2^{+}} = 0.5

H e X 2 X + \ce{He2^{+}} =0.5

H e X 2 \ce{He2} = 0

H X 2 \ce{H2} has the highest bond order. It also has the shortest bond length (74 pm) and highest bond energy (436 kJ/mol). H X 2 X + \ce{H2+} and H e X 2 X + \ce{He2^+} have the same bond order, and they both have bond lengths around 100 pm and bond energies around 250 kJ/mol. H e X 2 \ce{He2} has a bond order of 0 and is not observed in nature.

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