The Photoelectric Effect: A Problematic Problem

The maximum energy of photoelectrons emitted from potassium is 2.1 e V 2.1 eV when illuminated by light of wavelength 3 × 1 0 7 3 \times 10^{-7} m and 0.5 e V 0.5 eV when the light wavelength is 5 × 1 0 7 5\times 10^{-7} m. Use these results to obtain values for the minimum energy needed to free an electron from potassium, in e V eV .


The answer is 1.9.

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1 solution

We use the equation:

E x = h v ϕ E_x=hv-\phi , where E x E_x is the maximum electron energy, v v is the light frequency, ϕ \phi is the work function and h h is Planck's constant.

We also need to know that 1 e V 1 eV is equivalent to 1.6 × 1 0 19 J 1.6 \times 10^{-19}J , and we must remember that v = c / λ v=c/\lambda , where c = 3 × 1 0 8 m s 1 c=3 \times 10^8 ms^{-1} is the speed of light and λ \lambda is the wavelength, we get:

2 π × 1 0 15 h 2 ϕ = 3.36 × 1 0 19 2\pi \times 10^{15} \frac {h}{2}-\phi= 3.36 \times 10^{-19}

and

1.2 π × 1 0 15 h 2 ϕ = 0.8 × 1 0 19 1.2\pi \times 10^{15} \frac{h}{2}-\phi=0.8 \times 10^{-19} .

Solving these simultaneous equations gives h 2 = 1.02 × 1 0 34 J \frac{h}{2}=1.02 \times 10^{-34}J and ϕ = 1.9 e V \phi=1.9 eV .

We have thus found both the value of h h bar and the work function of potassium.

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