This is not what I have learnt at school

Chemistry Level 3

Describe the molecular shape of I C l X 6 X . \ce{ICl6-}.

See-Saw shaped Square Pyramidal Perfect Octahedran Distorted / Capped Octahedran

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1 solution

Pankaj Joshi
Jul 5, 2014

What I have learnt is that it is s p 3 d 3 sp^3d^3 with one lone pair, so technically it should be distorted octahedran, but the lone pair in this compound is present in stereochemically inactive s orbital . In simple language, the s - orbital does not take part in hybridisation or you can say that hybridiation of s orbital is ineffective. So lone pair goes into the s-orbital and its effect is uniformly ditributed over the whole compound, producing the result we have!

May i know how to decide whether the electron pair is present in the stereochemically active or inactive s orbital?

Nishanth Subramanian - 4 years, 3 months ago

how to decide whether the electron pair is present in the stereochemically active or inactive s orbital?

Gagan Sharma - 3 years, 3 months ago

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