Time Evolution of Stationary States

A particle in quantum mechanics has the non-normalized wavefunction at t = 0 t=0 :

ψ ( x ) = i ϕ 1 + ϕ 3 , \psi(x) = -i \phi_1 + \phi_3,

where the ϕ n \phi_n are the orthonormal eigenstates of some Hamiltonian with energies E n = 1 n E_n = \frac{1}{n} .

Find the normalized wavefunction ψ ( x , t ) \psi(x,t) at all times.

i e i t / ϕ 1 + e i t / ( 3 ) ϕ 3 -i e^{-it/\hbar} \phi_1 + e^{-it/(3\hbar)} \phi_3 i 2 ϕ 1 + 1 2 ϕ 3 -\frac{i}{\sqrt{2}} \phi_1 + \frac{1}{\sqrt{2}} \phi_3 i 2 e i t / ϕ 1 + 1 2 e 3 i t / ϕ 3 -\frac{i}{\sqrt{2}} e^{-it/\hbar} \phi_1 + \frac{1}{\sqrt{2}} e^{-3it/\hbar} \phi_3 i 2 e i t / ϕ 1 + 1 2 e i t / ( 3 ) ϕ 3 -\frac{i}{\sqrt{2}} e^{-it/\hbar} \phi_1 + \frac{1}{\sqrt{2}} e^{-it/(3\hbar)} \phi_3

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1 solution

Matt DeCross
May 10, 2016

Each energy eigenstate evolves according to its eigenstate by the factor e i E n t / = e i t / ( n ) e^{-iE_n t/\hbar} = e^{-i t/(\hbar n)} .

First, normalize the state by applying a factor of 1 2 \frac{1}{\sqrt{2}} to each term so that the total norm is one. Then, evolving ϕ 1 \phi_1 by e i t / e^{-it / \hbar} and ϕ 3 \phi_3 by e i t / ( 3 ) e^{-it / (3\hbar)} gives the solution.

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