Titrations

Chemistry Level 3

1 g 1 g sample of A g N O X 3 \ce{AgNO3} is dissolved in 50 50 m L mL of water. It is titrated with 50 50 m L mL of K I KI solution. The Silver Iodide precipitated is filtered off. Excess of K I KI in filtrate is titrated with M / 10 M/10 K I O X 3 \ce{KIO3} in presence of 6 M 6M H C l HCl till all I I^{-} is converted into I C l ICl . It requires 50 50 m L mL of M / 10 M/10 K I O X 3 \ce{KIO3} solution. 20 20 m L mL of the same stock solution of K I KI requires 30 30 m L mL of M / 10 M/10 K I O X 3 \ce{KIO3} under similar conditions. The reaction is : K I O X 3 + 2 K I + 6 H C l 3 I C l + 3 K C l + 3 H X 2 O \ce{KIO3} + 2KI + 6HCl → 3ICl + 3KCl + 3\ce{H2O}

The percentage of A g N O X 3 \ce{AgNO3} in the sample is :


The answer is 85.

This section requires Javascript.
You are seeing this because something didn't load right. We suggest you, (a) try refreshing the page, (b) enabling javascript if it is disabled on your browser and, finally, (c) loading the non-javascript version of this page . We're sorry about the hassle.

1 solution

Suhas Sheikh
Jun 13, 2018

Notice that comproportionation occurs here ( 2 different oxidation states change into a same oxidation state via reduction and oxidation separately) It is best to work with milimoles and figure out the milimoles used up by the AgNO3 sample to figure out weight of AgNO3 present I might write a full solution later

0 pending reports

×

Problem Loading...

Note Loading...

Set Loading...