sample of is dissolved in of water. It is titrated with of solution. The Silver Iodide precipitated is filtered off. Excess of in filtrate is titrated with in presence of till all is converted into . It requires of solution. of the same stock solution of requires of under similar conditions. The reaction is :
The percentage of in the sample is :
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Notice that comproportionation occurs here ( 2 different oxidation states change into a same oxidation state via reduction and oxidation separately) It is best to work with milimoles and figure out the milimoles used up by the AgNO3 sample to figure out weight of AgNO3 present I might write a full solution later